Diisopropylammonium methanesulfonate
نویسندگان
چکیده
The title molecular salt, C(6)H(16)N(+)·CH(3)SO(3) (-), has been determined at 150 K. Two diisopropyl-ammonium cations (dipH) and two anions form N-H⋯O hydrogen-bonded cyclic dimers lying around centers of symmetry. Only two of the three O atoms of the methane-sulfonate anion are involved in hydrogen bonding, resulting in slightly longer S-O bond lengths. The title structure represents an example of a sulfonate anion that is part of a hydrogen-bonding R(4) (4)(12) graph-set motif, which is well known for related dipH acetates. Additionally, the Raman and the IR spectroscopic data for the title compound are presented.
منابع مشابه
Bis(diisopropylammonium) naphthalene-1,5-disulfonate
In the title compound, 2C(6)H(16)N(+)·C(10)H(6)O(6)S(2) (2-), the cations and anions are associated via N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.
متن کاملDiisopropylammonium thiocyanate
In the title mol-ecular salt, C(6)H(16)N(+)·NCS(-), the cation possesses approximate local twofold rotation symmetry. One of its NH atoms forms a hydrogen bond to a thio-cyanate N atom and the other to a thio-cyanate S atom. This results in [001] chains of alternating cations and anions.
متن کامل(E)-1,2-Diphenylethenyl methanesulfonate
In the title compound, C(15)H(14)O(3)S, the dihedral angle between the two benzene rings is 59.3 (8)°. The crystal structure is stabilized by weak inter-molecular C-H⋯π inter-actions between the benzene rings and the central ethyl-ene bridge, and a weak non-classical C-H⋯O hydrogen bond occurs in the structure.
متن کاملDiisopropylammonium 4-methoxybenzoate
In the crystal structure of the title compound, C(6)H(16)N(+)·C(8)H(7)O(3) (-), inter-molecular N-H⋯O hydrogen bonds link the cations and anions into arrangements consisting of two cations and two anions each.
متن کامل2-Nitrobenzyl methanesulfonate
In the title compound, C8H9NO5S, the dihedral angle between the benzene ring and the nitro group is 5.86 (15)° and the C-C-O-S group adopts an anti conformation [torsion angle = -168.44 (15)°]. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, generating a three-dimensional network.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011